Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Communications in mathematical physics 40 (1975), S. 197-213 
    ISSN: 1432-0916
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Notes: Abstract The thermodynamic limit is taken using a sequence of regions all the same shape as a given region ω of volume |ω|, with a specified distribution of normal field component on ∂ω. We show that with magnetostatic interactions the limiting free energy density is bounded above by jhen where $$\bar f$$ (ϱ,B) is the free energy density for a system of density ϱ in a uniform external fieldB and the “inf” is taken over all divergence-free fieldsB with given normal component on ∂ω and all densities ϱ(x) compatible with particle number constraints of the form $$\int\limits_{\Gamma _i } {\varrho (x)d^3 x = \left| {\Gamma _i } \right|\varrho _i } $$ where Γi is a sub-region of ω. A physical argument suggests that this upper bound is the true thermodynamic limit, and that it takes account demagnetization effects. Electrostatic interactions can be treated similarly.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 17 (1977), S. 47-60 
    ISSN: 1572-9613
    Keywords: Surface phase transitions ; adsorption isotherms ; dense fluids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We derive adsorption isotherms for an adsorbate of hard-sphere particles with “sticky” interactions at any fluid density being adsorbed onto a plane, “sticky” surface. The theory is based on the Percus-Yevick theory for bulk fluids and explicitly includes the equilibrium between the adsorbed fluid and the bulk adsorbate. The theory predicts a surface condensation at low temperatures and low bulk densities in good agreement with surface condensations found in experimental studies of adsorption of gases onto graphite. An approximate law of corresponding states for these transitions is developed. At higher bulk densities and room temperatures, the adsorption isotherms can show a maximum, in accord with recent experimental work.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 21 (1979), S. 659-667 
    ISSN: 1572-9613
    Keywords: Ornstein-Zernike equation ; Baxter's factorization ; softcore ; Yukawa closure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A model for simple fluids is proposed in which the radial distribution function has a parametric form appropriate to a soft-core fluid for interparticle separationr ⩽ R, whereR is some range parameter. Forr 〉 R, the direct correlation function is assumed to be of Yukawa form. The Ornstein-Zernike equation is solved for this system, yielding the radial distribution and the total correlation function for the entire range of interparticle separation. Methods of relating the model fluid to a real fluid by assigning values to the parameters are discussed.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...