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  • 1975-1979  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 108 (1975), S. 146-154 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of Radioactive Metallocenes with 59Fe, 103Ru, and 191OsBy heating of inactive ferrocene derivatives with radioactive metall halides, i. e. 103RuCl3, radioactive metallocenes are synthesized with yields between 5 and 70% with 103RuCl3 or 59FeCl3 and nearly 1% with 191OsCl4. The radioactive metallocenes can be separated easily from radioactive by-products by TLC.
    Notes: Durch Erhitzen von nicht-radioaktiven Ferrocen-Derivaten mit radioaktiven Metallhalogeniden, z. B. 103RuCl3, gelingt die Synthese von radioaktiven Metallocenen. Die radiochemische Ausbeute bei der Reaktion mit 103RuCl3 oder 59FeCl3 beträgt 5-70%, mit 191OsCl4 knapp 1%. Die radioaktiven Metallocene lassen sich durch DC leicht von radioaktiven Nebenprodukten trennen.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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