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  • 1970-1974  (1)
  • Polymer and Materials Science  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 153 (1972), S. 219-228 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde die Verzweigung von durch Lauroylperoxid oder Bestrahlung initiiertem Polyvinylchlorid untersucht. Dabei zeigte sich, daß der Umsatz keinen Einfluß auf die Verzweigung hat. Diese dürfte, zumindest teilweise, seitlichen CH2Cl-Gruppen zuzuschreiben sein.Es wird ein Reaktionsmechanismus für eine solche Art der Verzweigung vorgeschlagen.
    Notes: An investigation was carried out on branching of polymers obtained by lauroyl-peroxide or by radiation-initiated polymerization of vinylchloride. As a result, branching shows no dependence on conversion and could be ascribed, at least partially, to the presence of CH2Cl-side groups.A reaction mechanism for this type of branching was proposed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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