ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The fragmentation reaction [C3(H,D)6]+· → [C3(H,D)5]+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH3CD=CH2,CD3CH=CD2 and CD3CH=CH2, CH3CD=CD2. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior to fragmentation. The isotope effect kH/kD is in the range 2·1 to 3·3.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210090602
Permalink