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  • 1970-1974  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 7 (1972), S. 435-440 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Electrical resistivity, Hall coefficient and thermoelectric power were measured on manganese silicides of composition MnSi2−x withx ranging from 0.25 to 0.28 in the temperature range from 80 to 1100K. At higher temperatures a forbidden energy gap estimated from the resistivity data was about 0.40 eV. It was confirmed that MnSi2−x was a degenerated semiconductor and that the hole concentrations in the degenerated state varied from 1.8 to 2.3×1021 cm−3. The ratio of electron to hole mobility was less than unity. The intrinsic resistivity and the hole mobility varied with temperature as 3.6×10−4 exp(2320/T) and 1.2×104 T −3/2 respectively. The value of Hall coefficient calculated by using a mobility ratio of 0.02 was in good agreement with that observed in the intrinsic region. From the relationship between hole concentration and thermoelectric power for MnSi1.73 near room temperature, the hole effective mass was estimated to be twelve times as large as the free electron mass. The calculation of the thermoelectric power was carried out based on the assumptions that the scattering of carriers is dominated by acoustic lattice scattering and that the carriers obey Fermi-Dirac statistics. The calculated results were in reasonable agreement with the observed thermoelectric powers in the temperature range from 150 to 1100K.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 7 (1972), S. 435-440 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Electrical resistivity, Hall coefficient and thermoelectric power were measured on manganese silicides of composition MnSi2−x withx ranging from 0.25 to 0.28 in the temperature range from 80 to 1100K. At higher temperatures a forbidden energy gap estimated from the resistivity data was about 0.40 eV. It was confirmed that MnSi2−x was a degenerated semiconductor and that the hole concentrations in the degenerated state varied from 1.8 to 2.3×1021 cm−3. The ratio of electron to hole mobility was less than unity. The intrinsic resistivity and the hole mobility varied with temperature as 3.6×10−4 exp(2320/T) and 1.2×104 T −3/2 respectively. The value of Hall coefficient calculated by using a mobility ratio of 0.02 was in good agreement with that observed in the intrinsic region. From the relationship between hole concentration and thermoelectric power for MnSi1.73 near room temperature, the hole effective mass was estimated to be twelve times as large as the free electron mass. The calculation of the thermoelectric power was carried out based on the assumptions that the scattering of carriers is dominated by acoustic lattice scattering and that the carriers obey Fermi-Dirac statistics. The calculated results were in reasonable agreement with the observed thermoelectric powers in the temperature range from 150 to 1100K.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 7 (1972), S. 1119-1124 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Single crystals of chromium disilicide about 8 mm in diameter and 35 mm long were grown using the floating zone technique. Measurements of electrical resistivity ρ, Hall coefficient R and thermoelectric power α were carried out in the temperature range from 85 to 1100 K. The values of ρ and α showed the anisotropy over the temperature range studied. The ratios parallel and perpendicular to the c-axis were ρ ‖/ρ ⊥=1.9 and α ‖/α⊥=1.7 respectively, at room temperature. It was found to be a degenerate semiconductor having the hole concentration of 6.3×1020 cm−3 below 600 K. The effective masses of holes parallel and perpendicular to the c-axis determined from the thermoelectric power and the hole concentration near room temperature were estimated to be five and three times as large as a free electron mass, respectively. The calculation on the values of α ‖ and α ⊥ was made using those effective masses. These values showed good agreement with the observed values in the temperature range from 150 to 1100 K.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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