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  • 1970-1974  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 86 (1974), S. 355-363 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Trotz sporadischer Untersuchungen in früheren Jahren blieben die Strukturen der meisten Pigmente unbekannt, welche Säugetierhaare und Vogelfedern gelb, orange und braun färben. Neuere Arbeiten ergaben, daß die Hauptpigmente, die rötlich-braunen Gallophaeomelanine, Polymere mit Benzothiazol- und Tetrahydroisochinolin-Einheiten sind. Daneben findet man die gelb-orange und violetten Trichochrome, die Δ2,2′-Bi(1,4-benzothiazin), einen neuen Chromophor, enthalten. In vivo entstehen beide Gruppen von Pigmenten aus Tyrosin und Cystein auf einem Weg, der vom Biogeneseweg der schwarzen Eumelanine abzweigt.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 13 (1974), S. 305-312 
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Despite sporadic investigations over many years the structures of the pigments responsible for most of the yellow, orange, and brown colors of mammalian hair, and of feathers, have remained unknown. However, recent work has shown that the major reddish-brown pigments, gallophaeomelanins, are polymers containing benzothiazole and tetrahydroisoquinoline units. The yellow-orange and violet trichochromes are minor pigments based on a new chromophore, Δ2,2′-bi(1,4-benzothiazine). Both groups arise in vivo from tyrosine and cysteine by a deviation from the biogenetic pathway which normally leads to the formation of eumelanins, the black pigments.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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