ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
EPR-Studies in the Thioamide Series, II1). N.N-Dialkyl-thiobenzamide Radical AnionsIt is shown by the EPR-spectroscopic coupling constants, having been unequivocally assigned by the aid of specifically deuterated derivatives, that N.N-Dialkyl-thiobenzamide radical anions exhibit a twisted conformation, the aromatic nucleus and the thiocarbamoyl group being rotated out of plane. - The spin density is shown to be predominantly located in the aryl residue.
Notes:
N.N-Dialkyl-thiobenzamid-Radikal-Ionen weisen eine Konformation auf, in der die Ebenen der Aryl- und Thiocarbamoyl-Gruppen gegeneinander verdreht sind. Dies zeigen die unter Zuhilfenahme spezifisch deuterierter Derivate zugeordneten EPR-Kopplungskonstanten. -Die Spin-Dichte ist dabei vorwiegend im Aryl-Rest lokalisiert.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.19707340102
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