Bibliothek

feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • 1990-1994  (4)
  • 1965-1969  (1)
Materialart
Erscheinungszeitraum
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 6161-6161 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Commercial perfluoro poly ethers (PFPE) are available with different backbone structures and end groups and are being used as lubricants for particulate/thin film disks. Very little published information is available other than F-19 spectra for these polymers.1 In this abstract a systematic study was undertaken to study the structure of these PFPE polymers using multinuclear magnetic resonance (NMR). Backbone structural differences of Z. Fomblin, Y. Fomblin, Krytox, and Demnums could be clearly seen from F-19 NMR studies. Number average molecular weight of PFPE polymers was also determined from F-19 NMR and found to be between 2000 and 10 000. C-13 NMR was used to differentiate the end group from backbone structure. Associated proton test (APT) was used to distinguish the primary, secondary, and tertiary carbons. The proton connectivity of end group (e.g., Fomblin AM2001) was studied by two dimensional (2D) proton correlation spectroscopy (COSY). The connectivity of a hydrogen containing end group to the backbone was studied by heteronuclear shift correlation spectroscopy (HCORR). Even though these PFPE polymers have low vapor pressure, a significant amount of lube loss is found over a period of time under HDA (head disk assembly) conditions.The temperature could increase from 25 to 60 °C. Additionally under certain asperity/head interaction conditions the temperature variation could be as high as 300 °C to 500 °C. It is also reported that functionalized polymeric materials (e.g., Krytox 143 AC) can be bonded to magnetic disk surface by applying heat. The effect of temperature on lubricant volatility/stability was studied for AM 2001. The molecular weight of heat treated AM 2001 (90 min at 130 °C) changed from 2100 to 4500. This could be due to preferential volatilization of low molecular weight fragments. NMR analysis showed significant conversion of piperonyl end group to -CH2OH. Thus AM 2001 is not thermally stable. Precipitation was also found to occur when AM 2001 is stored over a period of time. The precipitate is found to be a derivative of 9,10 dihydroanthracene. Unlike other PFPE polymers AM 2001 is found to be sparingly soluble in dichloromethane (contrary to the claim by the manufacturer that it is soluble only in fluorinated solvents) and hence more polar than Fomblin Z-Dol.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 945-954 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The anomalies of the second-, third-, and fourth-order elastic constants have been derived for barium titanate and related compounds for the phase transition from cubic to tetragonal and from the tetragonal to the orthorhombic phases. The equilibrium values of the three components of the order parameter and the strain variables in the two phases have been obtained from the stability conditions. The fluctuations in the order parameter in the two phases have been derived from the Landau–Khalatnikov equations. Expressions have been given for the shift in the zero point energy in the tetragonal and orthorhombic phases, and these are shown to be proportional to (T−Tc)2. The anomalies for all the second-order elastic constants have been derived for both phases, and relations among them have been reported. It is shown that the elastic anomalies suffer a discontinuity at the transition temperature for both the phases. Our expressions give the temperature variation of the third-order elastic and fourth-order elastic constants for the phase transition from the tetragonal to the orthorhombic phase.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    ISSN: 0992-7689
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Physik
    Notizen: Abstract A 54.95-MHz coherent backscatter radar, an ionosonde and the magnetometer located at Trivandrum in India (8.5○N, 77○E, 0.5○N dip angle) recorded large-amplitude ionospheric fluctuations and magnetic field fluctuations associated with a Pc5 micropulsation event, which occurred during an intense magnetic storm on 24 March 1991 (Ap=161). Simultaneous 100-nT-level fluctuations are also observed in the H-component at Brorfelde, Denmark (55.6○N gm) and at Narsarsuaq, Greenland (70.6○N gm). Our study of the above observations shows that the E-W electric field fluctuations in the E- and F-regions and the magnetic field fluctuations at Thumba are dominated by a near-sinusoidal oscillation of 10 min during 1730–1900 IST (1200-1330 UT), the amplitude of the electric field oscillation in the equatorial electrojet (EEJ) is 0.1-0.25 mV m−1 and it increases with height, while it is about 1.0 mV m−1 in the F-region, the ground-level H-component oscillation can be accounted for by the ionospheric current oscillation generated by the observed electric field oscillation in the EEJ and the H-component oscillations at Trivandrum and Brorfelde are in phase with each other. The observations are interpreted in terms of a compressional cavity mode resonance in the inner magnetosphere and the associated ionospheric electric field penetrating from high latitudes to the magnetic equator.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 4
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 55 (1992), S. 171-174 
    ISSN: 1434-6052
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We discuss a dynamical mechanism which may yield a natural chiral symmetry for fermions. The small fermion mass generated by various dynamical interactions is presented.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 5
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 6 (1967), S. 1-14 
    ISSN: 1434-6036
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Beschreibung / Inhaltsverzeichnis: Résumé On discute l'effet de corrélations dynamiques entre spins opposés sur l'énergie de l'état fondamental d'une paire d'atomes d'impurités avec interaction magnétique entre eux dans un métal normal. On obtient pour le fondamental du couple d'impurités magnétiques un état où les spins sont antiparallèles; autrement dit l'intéraction d'échange entre les états localisés est du type antiferromagnétique. Ce résultat est tres différent de celui prédit par la théorie de Hartree-Fock où le fondamental est soit ferromagnétique, sont antiferromagnétique selon la position, par rapport à l'énergie de Fermi, des énergies des électrons de spin haut et de spin bas. Les calculs sont faits en utilisant la technique des fonctions de Green dans l'approximation de la matricet.
    Kurzfassung: Zusammenfassung Der Einfluß der dynamischen Korrelationen zwischen Elektronen entgegengesetzten Spins auf die Energie des Grundzustandes eines Paares von Störatomen mit magnetischer Wechselwirkung in einem normalen Metall wird untersucht. Es zeigt sich, daß im Grundzustand eines solchen Systems die Spins der magnetischen Störatome antiparallel angeordnet sind. Die Wechselwirkung zwischen den lokalisierten Zuständen ist also antiferromagnetisch. Dieses Resultat steht in scharfem Gegensatz zur Aussage der Hartree-Fock-Theorie, nach welcher der Grundzustand des Systems ferro- oder antiferromagnetisch sein kann, je nach der Lage der Energien der Elektronen mit aufwärts und abwärts gerichtetem Spin relativ zur Fermienergie. Die Berechnung wird mit der Methode der Greenschen Funktionen in dert-Matrix-Näherung durchgeführt.
    Notizen: Abstract The effect of including dynamical correlations between electrons of opposite spins in determining the ground state energy of a pair of magnetically interacting impurity atoms in an otherwise normal metal is discussed. It is found that in the ground state of such a system the spins of the magnetic impurity atoms are aligned antiparallel. In other words, the interaction between the localized states is of antiferromagnetic exchange type. This result differs sharply from that predicted by the Hartree-Fock (H-F) theory, in which the ground state of the system can be either ferro- or antiferromagnetic, depending on the energies of the spin up and spin down electrons relative to the Fermi energy. The calculations are performed using many-body Green's function techniques in thet-matrix approximation.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...