ISSN:
0449-296X
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The mechanism of the reaction of tetraethylenepentamine (TEPA) with cumene hydroperoxide (CHP) and iron ions was investigated. It was found that (1) TEPA did not reduce Fe(III); (2) TEPA was consumed by this reaction; (3) both Fe(II) and Fe(III) were effective for this reaction. It was shown that though the O—O bond of a hydroperoxide could be cleaved only at elevated temperatures, it could be easily cleaved by the reaction with the iron-TEPA complex. The function of this iron-TEPA complex is discussed.
Zusätzliches Material:
2 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1969.150070226
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