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  • 1960-1964  (3)
  • Chemistry  (3)
  • 15A48
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 149-154 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for using an adiabatic reactor to study the kinetics of reactions of gases on solid catalysts. The method is based on measurement of the steady state axial profile of temperature or composition in a specially designed adiabatic packed bed reactor. Reaction rates are calculated from these measured profiles by graphical differentitation. The method is applicable for multireaction systems and for any type of kinetic behavior.The method was demonstrated by an experimental study of cumene cracking an silica-alumina catalyst at 420° to 480°C. The measured reaction rates are in satisfactory agreement with results obtained by other investigators who used isothermal reactors. Areas of application of the adiabatic method are suggested.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 45 (1960), S. 189-194 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Kinetic measurements have been made on the bulk polymerization of styrene at 30 and 60°C. in the redox system dimethylaniline-benzoyl peroxide. From these measurements it has been ascertained that the kinetic behavior of this system at higher temperatures is the same as that at lower temperatures. The decomposition rate constant and the efficiency in initiating polymerization were determined. It has also been shown that neither the amine nor the products of the amine-peroxide reaction affect the propagation of the polymerization.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 76 (1964), S. 604-604 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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