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Mechanism of amine crosslinking of fluoroelastomers. I. Solution studies (1960)

Paciorek, K. L. ; Mitchell, L. C. ; Lenk, C. T.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 45 (1960), S. 405-413

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Solution studies of Kel-F elastomer and Viton A with various amines have shown that dehydrohalogenation is the primary step in crosslinking and usually proceeds at temperatures lower than those required for gelation. There is a difference in the reactivity between the two polymers; dehydrohalogenation and gelation occur more readily with Kel-F elastomer than with Viton A. The rate of reaction and temperature at which gelation is observed depend upon the type of amine. Mechanisms of crosslinking are proposed and discussed.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1960.1204514610

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