ISSN:
1573-9171
Keywords:
[2-(dimethylaminomethyl)cymantrenyl]lithium
;
ytterbium diiodide
;
[2-(dimethylaminomethyl)cymantrenyl]ytterbium iodide
;
bis[2-(dimethylaminomethyl)cy-mantrenyl]ytterbium
;
electrophiles
;
derivatives of cymantrene
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of [2-(dimethylaminomethyl)]cymantrenyl]lithium with ytterbium diiodide affords [2-(dimethylaminomethyl)cymantrenyl]ytterbium iodide or bis[2-(dimethylaminomethyl)cymantrenyl]ytterbium depending on the ratio of the starting reactants. Reactions of these complexes with a series of electrophiles (H2O, Me3SiCl, MeCOCl, HgCl2, PhCOCl) were studied and the corresponding derivatives of cymantrene were prepared in high yields.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01169733
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