ISSN:
0009-2940
Keywords:
Gold
;
Polygoldammonium salts
;
(1-Adamantyl)ammonium salts
;
Trinuclear complex, X-ray structure of
;
Tetranuclear complex
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of 1-adamantylamine with tris(triphenylphosphaneaurio)oxonium tetrafluoroborate results in the formation of the trinuclear adamantyltris(triphenylphosphaneaurio)ammonium tetrafluoroborate {C10H15[Au(PPh3)]3}+BF4-. The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex {C10H15N[Au(PPh3)]4}2+(BF4minus;)2. Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X-ray structure determination.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300213
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