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  • (La, Ca)2CaCu2O6, single crystal  (1)
  • 81.10  (1)
  • 1
    ISSN: 1432-0630
    Keywords: 68.35 ; 81.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract C70 single crystals, free from solvent contamination, were grown via vapor phase transport technique. The (0001) face of the C70 crystal was imaged with Atomic Force Microscopy (AFM) under ambient atmosphere. Low-resolution images of a freshly prepared crystal revealed well-ordered faceted regions with multiple terraces extending over a region of several hundred square nanometers. The terraced structure in the images indicates that the crystals formed as a layer growth. In the high-resolution images, C70 molecules were resolved in a hexagonal close packed (hcp) structure with an average center-to-center distance of 10.5±0.5 Å. After one month's exposure to the ambient atmosphere, the molecules rearranged into a mixed structure consisting of hcp and face centered cubic (fcc) regions.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9605
    Keywords: (La, Ca)2CaCu2O6, single crystal ; TSFZ technique ; oxygen HIP ; electrical anisotropy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Large single crystals of (La1−x Ca x )2CaCu2O6 were synthesized by the travelling solvent floating zone (TSFZ) technique. The dimension of the grown boules was typically 4 mmφ×30 mm long with thec-axis perpendicular to the growth direction. After oxygen loading at 1080°C in 400 atm of O2, they became superconductive with a sharp transition at around 50 K. The resistivity was metallic both along thec-axis and within theab-plane, with an anisotropy ratio ofγ 2≡(ρ c/ρ ab ) ∼ 50 which is almost independent of temperature. Details of the crystal growth, heat treatment procedures, and the results of electrical and magnetic property measurements are presented.
    Type of Medium: Electronic Resource
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