ISSN:
0009-2940
Keywords:
1-Naphthalenecarbonitrile, photochemistry of
;
Cyclobutanes
;
Captodative substitution
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Photoexcited 1-naphthalenecarbonitrile (1) adds 2-morpholinoacrylonitrile (2) in the [2 + 2] mode both at the C(1) - C(2) and C(7) - C(8) bond unidirectionally and with the formation of only one (3 and 4, respectively) of the two a priori possible stereoisomers in each case. The structure of 3 has been unambiguously confirmed by an X-ray structural analysis.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260132
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