ISSN:
0749-1581
Keywords:
77Se NMR
;
13C NMR
;
1H NMR
;
Phenylselenenylazidocyclohexanes
;
Phenylselenenylchlorocyclohexanes
;
1-Phenylselenenylmethylcyclohexene conformation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The 77Se, 13C and 1H NMR spectra of the products of phenylselenenyl azide and chloride addition to methylenecyclohexane and cyclohexene are presented. Scalar couplings between 77Se and 1H/13C allowed the absolute assignment of the regioisomers in the 1H and 13C spectra. Low-temperature 77Se NMR was used to determine the conformer ratios for 1-azidomethyl- and 1-chloromethyl-1-phenylselenenylcyclohexane anti-Markovnikov addition products.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260320502
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