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Study of the distribution of the π-electrons in push-pull alkenes by 1H and 13C NMR spectroscopy (1991)

Fischer, G. ; Rudorf, W.-D. ; Kleinpeter, E.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 29 (1991), S. 212-222

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ISSN: 0749-1581

Keywords: Dynamic NMR ; 13C NMR ; Push-pull alkenes ; Restricted C,C and C,N rotation ; π-Electron density distribution ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Push-pull alkenes with variable structure were investigated with respect to the influence of the different substituents at the central C,C double bond on the dynamic behaviour of this type of compound. 1H and 13C NMR spectroscopic investigations were carried out for ketene-S,S-, -S,N- and -N,N-acetals. HMO calculations were employed to discuss the related π-electron density distributions.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260290305

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