ISSN:
0749-1581
Keywords:
109Ag NMR
;
Chelated silver(I) diphosphine complexes
;
31P and 109Ag chemical shifts
;
1J(109Ag,31P) value 2D 31P-{109Ag} NMR
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The 109Ag NMR spectrum of [Ag(Ph2PCH=CHPPh2)2]NO3, a complex with antimicrobial and antitumour activity, was obtained using a retro-INEPT two-dimensional 31P-{109Ag} pulse sequence. This allowed the measurement of the 31P and 109Ag chemical shifts and the 1J(109Ag,31P) coupling constant in a single 2 h experiment and offered a considerable signal-to-noise gain compared with 109Ag-{31P} INEPT measurements.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260280210
Permalink
