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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 1 (1986), S. 151-156 
    ISSN: 1434-6079
    Keywords: 32.90 ; 32.30 ; 35.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract By optical interference and VUV spectroscopy the doublet system of SbI 5p 26s was investigated, so that now the hyperfinestructure of all 8 levels of 5p 26s (A- andB-splitting constants) are known. From the analysis we receive a spin-orbit parameter ζ5p =3,538(57) cm−1 and from the hyperfine-analysis single electron splitting constantsa 5p 01 =52.4(4.6),a 5p 10 =−1.6(7.3),a 5p 12 =72.3(2.3),a 6s 10 =91.7(4.1),b 5p 02 =−49.6(1.1) andb 5p 11 =30.4(3.2) (all values in mK). For all calculations in the fs- and hfs-analysis the 5p 26s 2 D 3/2 has to be excluded (see discussion). With the figures given above the quadrupole moment121 Q(5p 26s)=−0.44(3) barn was obtained. It is in good agreement with the121 Q(5p 3). For the core-polarization by the 5p electron in the innerfieldns-shells (n=1, 2, 3, 4, 5) and the unpaired 6s electron a field of +500(300) kG was obtained.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-6079
    Keywords: 32.30 ; 32.90 ; 35.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract From 17 transitions in the singly ionized Sb II spectrum the hyperfine structure (A andB splitting constants) of the complete excited configurations 5p6s and 5p6p were determined by means of optical interference spectroscopy. In addition, a theoretical analysis both of the fine structure and also of the hyperfine structure was carried out (in the case of 5p6p of the general typenpn′p for the first time in literature). For the 3 levels 5p6p 3 P 1, 5p7p 3 D 2 and 5p6p 1 P 1 a different classification was found and consistent values for the fine structure parameters, mixing coefficients and single electron hyperfine structure splitting parametersa nl ik andb nl ik were obtained. The three new determinations in Sb II of the quadrupole moment (in barn) of121Sb (Q(5p6s)=−0.55(5);Q(5p6p)=−0.57(5) from the 5p-electron andQ(5p6p)=−0.7(2) from the 6p-electron) are well agreeing with each other but differ to former values from SbI. The core polarization and isotope shift of the lines, however, are compatible with our former results in SbI.
    Type of Medium: Electronic Resource
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