ISSN:
1434-6079
Schlagwort(e):
36.40.+d
;
33.60.Cv
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Physik
Notizen:
Abstract We have measured the photoelectron-spectra of I− (H2O)n clusters in the size range n=1–60. We have found that the first six water molecules form a solvation layer with an average 0.35 eV electrostatic stabilization of the anion. At larger cluster sizes the electrostatic stabilization of water does not fit a continuous dielectric solvent. The most stable structures of the clusters consist of internally solvated anions. In the size range n=34–40 we have found evidence for existence of cluster structures with surface solvated anions.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01429115
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