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Analytical interaction potentials of the long range alkali-metal dimers (1996)

Marinescu, M. ; Dalgarno, A.

Springer

The European physical journal 36 (1996), S. 239-248

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ISSN: 1434-6079

Keywords: 34.20.Cf ; 31.15. − p ; 33.90. + h

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract Using almost degenerate perturbation theory the calculation of long range limits of alkali-metal dimer molecular states which dissociate to the atom pairs S1/2-P1/2, 3/2 and S1/2-D3/2, 5/2 is presented. Hund's coupling casec is adopted. The calculation includes correlations up to the second order of perturbation theory and exchange energy contributions. The results are expressed in a simple analytical form in terms of dispersion coefficients.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01426409

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