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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 26 (1993), S. 352-354 
    ISSN: 1434-6079
    Keywords: .64.70.Fx ; 36.40.+d ; 35.20.Vf
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In this paper, we report properties of selenium clusters produced by vapor condensation technique. Impact electronic ionization is performed on clusters in the size range from 2 to 36 atoms. The measured ionization potentials exhibit small oscillation corresponding to the wiggles observed on the mass distribution. An attempt to connect these experimental observations with the geometrical structure of the molecules is made in the discussion.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 26 (1993), S. 137-139 
    ISSN: 1434-6079
    Keywords: 36.40.+d ; 35.20.Vf ; 33.80.Eh
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Laser photoionization experiments have been performed on a large size range of indium and thallium clusters. The metal clusters were produced by laser vaporization technique and analyzed after laser ionization by standard time-of-flight mass spectrometry. For the indium clusters, individual ionization potentials (IP) are deduced for N≤132. Abrupt decreases in the IP values are observed, which correspond to the openings of new electronic shell as predicted by the spherical jellium model. For larger indium clusters, the unresolved mass spectra present small but reproducible oscillations. Interpretations in terms of either electronic shell structure or cluster geometry remain undecided for the moment. Our results on thallium clusters are less abundant and only qualitative. Nevertheless, they show that thallium behaves more like a monovalent element than like a trivalent one.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-6079
    Keywords: 35.20.Vf ; 36.40.+d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Antimony clusters are produced by the inert gas condensation technique. They are found to be built from Sb4 units. The fragmentation by evaporation of Sb4 units is studied as a function of the excess energy in the cluster. By this way the binding energy of the Sb4 units in the cluster is found to be about 1.5 eV, well below the binding energy of a Sb atom in the bulk and in Sb4(≃3eV). The evolution of ionization potentials of Sb4n clusters confirms that their structure is probably non metallic. Finally the possible metastable character of this Sb4n structure is discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 12 (1989), S. 411-413 
    ISSN: 1434-6079
    Keywords: 35.20.Vf ; 36.40.+d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Indium clusters are produced by the inert gas condensation technique. The ionization potentials are found higher for small clusters than for the Indium atom. This is explained by thep character of the bonding as in Aluminium. Doubly charge clusters are also observed and fragmentation processes discussed. Finally small Indium clusters 3〈n〈9 are found very reactive with hydrocarbon.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 19 (1991), S. 191-193 
    ISSN: 1434-6079
    Keywords: 35.20.Vf ; 36.40. +d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Rare earth clusters are produced by the inert gas condensation technique. The observed size distribution shows large peaks atn=13, 19, 23, 26, 29, 32, 34, 37, 39, 45, ... The beginning of this sequence (up to 34) has been already observed in argon clusters and recently by our group in barium clusters; this sequence may be interpreted in terms of icosahedral structures corresponding to the addition of caps on a core icosahedron of 13 atoms.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 19 (1991), S. 237-239 
    ISSN: 1434-6079
    Keywords: 35.20.Vf ; 36.40. +d
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Selenium and tellurium clusters are produced by the inert gas condensation technique. The mass spectra of both species are completely different and reveal different properties. In selenium, a periodicity of 6–7 is observed and may be interpreted by the binding energy between small cyclic molecules. Moreover, it was very difficult to obtained large clusters probably because the binding energy between these molecules is very small. In tellurium, these periodic structures do not exist and large clusters are easily obtained in nucleation conditions where only small selenium clusters are present. These results are discussed and a simple nucleation model is used to illustrate this different behavior. Finally these clusters properties are correlated to the bulk structure of both materials.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 26 (1993), S. 92-94 
    ISSN: 1434-6079
    Keywords: 36.40.+d ; 03.65.Sq ; 33.80.Eh ; 35.20.Vf
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Neutral aluminum clusters have been produced by laser vaporization technique, ionized by a low-power near-threshold laser light and detected using standard TOF spectrometric methods. Ionization potentials have been deduced in the low size range. In the large size range 250〈N〈1400 the patterns of the mass spectra exhibit a regular and continuous oscillation, originating from size-dependent ionization threshold effects. The period, constant on a Ne 1/3 scale (Ne=3N is the number of valence electrons), is approximately two times shorter than the one observed in alkali experiments. This feature is analyzed in terms of shell structure.
    Type of Medium: Electronic Resource
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