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Digitale Medien

Reactivity and stability of bimetallic clusters (1991)

Nonose, S. ; Sone, Y. ; Kaya, K.

Springer

The European physical journal 19 (1991), S. 357-359

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Details

ISSN: 1434-6079

Schlagwort(e): 36.40. + d ; 35.20. Wg ; 82.65. − i

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract Using two independent vaporization lasers, bimetallic clusters composed of transition elements and A1 were generated by the laser vaporization method. Reactivity toward hydrogen adsorption of bimetallic clusters was compared with genuine clusters. It was found that A1 which has no reactivity toward hydrogen plays a role of either inhibitor or accelerator of the reaction when A1 is mixed with Nb or Co. Unusual stability of Co12 V1 in contrast to the high reactivity of Co12–13 is attributed to the rigid geometric structure where V occupies the central position.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01448328

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