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Structure of nm-sized InSb clusters formed by spontaneous alloying (1994)

Yasuda, H. ; Mori, H. ; Muraki, T. ; [weitere]

Springer

The European physical journal 31 (1994), S. 209-212

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Details

ISSN: 1434-6079

Schlagwort(e): 61.16.Di ; 36.40. + d ; 66.30. − h

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract The alloying behavior of antimony atoms into nm-sized indium clusters has been studied in situ by TEM. When antimony atoms are vapor-deposited onto nm-sized indium clusters, a rapid dissolution of antimony atoms into indium clusters takes place and as a result InSb compound clusters are successfully formed. Such spontaneous alloying occurs even at ambient temperature. InSb clusters thus formed have the wurtzite structure. When these InSb clusters are annealed at 533 K, their structure changes into the sphalerite structure, which is the structure of the equilibrium phase of the bulk In50Sb50. The appearance of wurtzite-type InSb by spontaneous alloying is discussed in terms of ionicity of bonds in InSb.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01437838

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