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Dimroth-Umlagerung von Iminen des 1,5-Diaminotetrazols (1990)

Moderhack, Dietrich ; Goos, Karl-Heinz ; Preu, Lutz

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1575-1578

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ISSN: 0009-2940

Keywords: 5-Tetrazolamines, 1-(methylenamino)- ; Dimroth rearrangement ; (5-Tetrazolyl)hydrazones ; Cyanohydrazones, reaction with hydrogen azide ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Dimroth Rearrangement of Imines Derived from 1,5-DiaminotetrazoleHeating the imines 1 in dimethyl sulfoxide (or partly in xylene) provides hydrazones such as 2. The reaction is greatly favoured by electron-withdrawing groups attached to the imine carbon atom.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19901230719

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