ISSN:
0887-624X
Keywords:
bisnadimide
;
ring-opening metathesis polymerization
;
5-norbornene 2,3-dicarboximide
;
nadic anhydride
;
thermal stability
;
char yield
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The article deals with synthesis, characterization, and polymerization of 5-norbornene-2,3-dicarboximide end-capped resins (bisnadimides) based on 4,4′-diaminodiphenylether, 1,4/1,3-bis(4′-aminophenoxy) benzene, 2,2′-bis[4-(4′-aminophenoxy)phenyl]propane, and bis[4-(4′-aminophenoxy)phenyl]sulphone. Both exo and endo bisnadimides were prepared by reacting the aromatic diamines with exo or endo nadic anhydride in glacial acetic acid at 120°C. The exo or endo bisnadimides could be distinguished on the basis of differences observed in IR or 1H-NMR spectra. Both thermal (in solid state) and metathetical polymerization (using WCl6/tetramethyltin catalyst and chlorobenzene solvent) of bisnadimides was carried out. Only exo bisnadimides could be polymerized using metathesis reaction whereas thermal polymerization of both endo and exo bisnadimide could be successfully carried out at 300°C in static air atmosphere. The polymers were highly crosslinked and insoluble in common organic solvents. The polymers obtained by metathesis polymerization were light brown in color whereas those obtained by thermal polymerization were dark brown in color. Thermal stability of the thermally polymerized exo or endo bisnadimides was comparable. These polymers were stable up to 400°C and decomposed in a single step above this temperature. The char yield at 800°C depended on the structure of the polymer and was in the 39-56% range. The polymers formed by metathesis polymerization showed a 1-3% weight loss in the temperature range 226-371°C and decomposed in a single step above 440°C. The char yields were higher in these polymers (53-71%) compared to those obtained by thermal polymerization. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2323-2331, 1997
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
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