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  • A4, A9, A5 and A3  (1)
  • Chapman-Enskog solutions  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 14 (1976), S. 469-481 
    ISSN: 1572-9613
    Schlagwort(e): Chemical kinetics ; nonequilibrium statistical mechanics ; correlation functions ; Boltzmann equation ; Chapman-Enskog solutions ; inelastic relaxation ; projection operator
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The relaxation of an internal state distribution in the presence of an excess of an inert gas is considered. The explicit time dependence of the nonequilibrium contributions to the transition rate coefficients is approximated using the Kapral-Hudson-Ross method. The resulting solution contains cross-correlation terms which do not appear when a single reaction is considered. It is shown that the first term of a perturbation expansion of an exact formal solution gives the Kapral-Hudson-Ross solution for short times, and the Chapman-Enskog solution at long times if there is a wide separation in time scales. The Kapral-Hudson-Ross, Chapman-Enskog, and exact solutions are compared for a two-state, hard-sphere model system.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    ISSN: 1573-5087
    Schlagwort(e): elongation ; gibberellins ; A4, A9, A5 and A3 ; le mutant ; Pisum
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Gibberellin A4 (GA4) was identified for the first time in the garden pea (Pisum sativum) L.), by gas chromatography-mass spectrometry. However, in wild-type shoots the level of GA4 was only about 6% of the level of GA1, and it is therefore unlikely that GA4 plays a major role per se in the control of pea stem elongation. In shoots of the le mutant, GA4 was not detected, while the level of GA9 was approximately twice that found in the wild-type. The le mutation also markedly reduced the elongation response to applied GA9. It appears, therefore, that in Pisum the le mutation blocks the 3β-hydroxylation of GA9 to GA4, in addition to the 3β-hydroxylation of GA20 to GA1. In contrast, the le mutation did not reduce the response to applied GA5, suggesting the step GA5 to GA3 is not catalysed by the enzyme controlled by the Le gene. The step GA5 to GA3 was confirmed in peas by metabolite analysis after treatment with deuterated GA5.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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