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  • APCI mass spectrometry  (1)
  • Silver  (1)
  • 1
    ISSN: 1573-5036
    Keywords: Fulvic acids ; Humic acids ; Lolium perenne L. ; Silver
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary An experiment in which perennial ryegrass (Lolium perenne L.) was grown in solution cultures containing various forms of radiosilver (110mAg) is ptake of labelled Ag from solutions containing either AgNO3, Ag2SO4, AgCH3COO, Ag-humic acid (HA) or Ag-fulvic acid (FA) complexes is compared. In each case concentrations of Ag in the plant roots was several fold higher than in the plant shoots. However the Ag concentration in roots from the Ag-HA preparations was only about 5% of that from the AgNO3 solutions; from Ag-FA it was 18%. Transport index values were highest for plants grown in the Ag-HA solution, indicating greater mobility of Ag within these plants. Preliminary data for a selective extraction procedure performed on Ag-HA preparations suggest sorption onto various active sites. The relevance of these findings to the cycling of Ag within soils is discussed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Evaporative light scatering detection ; APCI mass spectrometry ; Triacylglycerols
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Short- and long-chain triacylglycerols (SLCT) are a family of lipids prepared by chemical or enzymatic interesterification of triacetin, tripropionin and/or tributyrin, and long-chain (C16!18) hydrogenated vegetable oils. In this study, a normal-phase cyanopropyl high-performance liquid chromatographic (HPLC) method was developed for the separation and quantification of SLCT. The method is capable of separating SLCT mixtures, free fatty acids and the neutral lipid classes of saturated long-chain triacylglycerols, diacylglycerols and monoacylglycerols. To characterize the specific SLCT classes, a normal-phase HPLC procedure using a non-modified silica column was developed to separate the SLCT into individual isomers based on total carbon number and position of fatty acids on the glycerol backbone. Online coupling with a mass detector (LC/MS) allowed the identification of the individual triacylglycerol structures.
    Type of Medium: Electronic Resource
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