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  • Artikel: DFG Deutsche Nationallizenzen  (2)
  • Acidity  (2)
  • 1
    Digitale Medien
    Digitale Medien
    Microcalorimetric studies of zeolite acidity (1992)
    Springer
    Catalysis letters 12 (1992), S. 201-211 
    Details
    ISSN: 1572-879X
    Schlagwort(e): Acidity ; gravimetry ; heat of adsorption ; H-Mordenite ; H-Y ; H-ZSM-5 ; microcalorimetry ; pyridine ; zeolite
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The acidity characteristics of H-ZSM-5, H-Mordenite and H-Y zeolite have been studied by microcalorimetric and gravimetric measurements of pyridine adsorption. H-ZSM-5 and H-Mordenite have Brønsted acid sites of primarily homogenous strength, with H-Mordenite having the stronger sites, whereas H-Y zeolite had Brønsted sites of varying strength. The effects of Na exchange level in H-Y zeolite and high temperature calcination for H-Mordenite have also been examined.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00767202
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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    Artikel (Nationallizenzen)
    Volltext
  • 2
    Digitale Medien
    Digitale Medien
    Thermogravimetric and microcalorimetric studies of ZSM-5 acidity (1993)
    Springer
    Catalysis letters 18 (1993), S. 183-192 
    Details
    ISSN: 1572-879X
    Schlagwort(e): Acidity ; zeolites ; microcalorimetry ; thermogravimetry ; pyridine adsorption
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The combination of thermogravimetry, microcalorimetry and infrared spectroscopy studies of pyridine adsorption has been used to characterize the acidity of a ZSM-5 catalyst. The majority of the acid sites are Brønsted acid centers associated with framework Al species, with heats of pyridine adsorption equal to 140 kJ/mol. Non-framework Al species in the zeolite sample of this study eliminate an approximately equal number of Brønsted acid sites. These nonframework Al species also produce strong Lewis acid sites with pyridine adsorption heats greater than 140 kJ/mol, as well as weak adsorption sites (e.g., weak Bransted acid sites or hydrogen bonding sites) with heats equal to 90–140 kJ/mol.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00769437
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
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