ISSN:
1432-1327
Keywords:
Key words Fe(III) monomer and dimer
;
Lipophilic pyridinone
;
MeOH/H2O mixed solvent
;
Activation volume
;
Kinetics and mechanism
Source:
Springer Online Journal Archives 1860-2000
Topics:
Biology
,
Chemistry and Pharmacology
Notes:
Abstract The kinetics of Fe(III) complexation by lipophilic 3-hydroxy-2-methyl-l(γ-stearoamidopropyl)-4-pyridinone (HMSP) were studied when [Fe(III)] 〉 [HMSP] in MeOH/H2O mixed solvent and [Fe(III)] 〈 [HMSP] in MeOH, respectively. When Fe(III) was in excess, the observed rate constants depend on [Fe(III)]2 tot and on the reciprocal of [H+] and decrease with increasing pressure. ΔV
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/s007750050189
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