ISSN:
0009-2940
Keywords:
Carbonyllithium compounds
;
Acyllithium compounds
;
IR spectroscopy in liquid xenon
;
Calculations, ab initio
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Solutions of alkyl- or aryllithium compounds were treated with CO or tBu-NC in liquid xenon (LXe) at low temperature. Carbonyllithium compounds, acyllithium and the corresponding isolobal isonitrile products were characterized by IR spectroscopy for the first time. The structures, energies and characteristic IR frequencies of the intermediates were calculated by using ab-initio methods and discussed with the experimental values.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19951281015
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