ISSN:
1572-879X
Keywords:
Addition reactions
;
cobalt(II) catalyst
;
free radicals
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The cobalt(II)-2-methylpropylamine complex is an efficient catalyst for addition of tetrachloromethane to alkenes under mild reaction conditions (80 °C) providing 1 ∶ 1 adducts up to 99.5% yield. Reactions with vinyl monomers provided low yield of 1 ∶ 1 addition products (5–48%) presumably due to radical chain processes favoring telomerization and polymerization.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00765280
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