ISSN:
0009-2940
Keywords:
2-(2-Pyridyl)phosphinines
;
2,2′-Biphosphinines
;
Transition metals
;
Biphosphinine chelates
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis and coordination chemistry of 2-(2-pyridyl)-phosphinines and 2,2′-biphosphinines are reviewed. A noteworthy series of homoleptic complexes of 4,4′,5,5′-tetramethyl-2,2′-biphosphinine (tmbp) with Cr(0), Mo(0), Wo(0) and Ni(0) are described. A [Cu(bpy)(tmbp)]+ cationic polymer has been characterized by X-ray analysis. Ruthenium, manganese and rhenium chelates were also obtained. With Mn2(CO)10, a (tmbp)-Mn2(CO)6 complex is formed where tmbp acts as an eight electron donor.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961290303
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