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Digitale Medien

Reaktion von primären Alkylhydroperoxiden mit Amidoschwefelsäurechlorid: Alkyl(amidosulfonyl)peroxide (1984)

Blaschette, Armand ; Safari, Hassan

Springer

Monatshefte für Chemie 115 (1984), S. 875-880

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Details

ISSN: 1434-4475

Schlagwort(e): Sulphamoyl chloride, reaction withn-alkyl hydroperoxides ; n-Alkyl hydroperoxides, reaction with sulphamoyl chloride ; Alkyl(sulphamoyl)peroxides, preparation and thermolysis

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The novel peroxides H2NSO2OOCH2 R (1 a:R=CH2CH3;1 b:R=CH2CH2CH3) are obtained by reaction of sulphamoyl chloride with the appropriate hydroperoxides in the presence of pyridine (temperature below −30 °C, solvent diethyl ether). The solvent-free liquids1 deflagrate at ca. 0 °C. Hydrolysis or ammonolysis of1 generates the hydroperoxide and sulphamic acid or sulphamide, respectively. Controlled thermolysis of1 affords sulphamic acid and carbonyl compounds, i.e. propanal andn-propyl propanoate from1 a, butanal, 2-methylpropanal andn-butyln-butyrate from1 b. These products suggest a nonradical cyclic decomposition path-way.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00798755

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