ISSN:
0009-2940
Keywords:
Tripod ligands
;
Cobalt complexes
;
Allyl complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Preparation and Structure of Allyl(tripod)cobalt(I) and the Comparison with the Analogous Cobalt(I) ComplexThe synthesis of the 18-electron diamagnetic allyl(tripod)cobalt(I) complex [{CH3C(CH2PPh2)3}Co(η3-C3H5)] (1) is presented. Its structure is established by the usual analytical techniques as well as by X-ray analysis, and it is proved to be significantly different from that of the cationic 17-electron species 1+.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19951280218
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