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Resonant Raman excitation profile of the 220 cm-1 mode in trans-azobenzene (1992)

Biancalana, A. ; Campani, E. ; Gorini, G. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 23 (1992), S. 155-160

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Details

ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The Raman excitation profile for the 220 cm-1 mode of trans-azobenzene in cyclohexane solution was measured in resonance with the π-π* transition peaked around 320 nm. A strong modulation of the band intensity across the first vibrational feature of the poorly resolved absorption spectrum was detected. The collected data were analysed by means of the time-correlator theory and of a Franck-Condon model to derive some molecular parameters of the excited electron state.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250230306

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