ISSN:
0951-4198
Schlagwort(e):
Chemistry
;
Analytical Chemistry and Spectroscopy
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Physik
Notizen:
A new mass spectrometry technique using an inductively coupled plasma (ICP) ionization source and an ion-trap mass spectrometer (ITMS) detector is described and evaluated for elemental and isotopic analysis. Initial results obtained with the ICP-ITMS technique include sub-ppb detection of bare ions for, most elements, complete destruction of typical polyatomic matrix ions (e.g., CIO+, ArO+, and ArCl+), and effective neutralization of strong Ar+ ion currents. The latter effects allow observation of clearer mass spectra at m/z 〈 80 and potentially improved detection of ‘problem’ elements in ICP-MS (e.g., K, Ca, V, Fe, As, and Se). Formation of poly-oxide and -hydroxide ions of metals with high oxide bond strengths were observed and require system modifications to alleviate.
Zusätzliches Material:
8 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/rcm.1290080114
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