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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 1037-1037 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 526-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 931-939 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Flow parameters were measured in a baffled, turbulent, stirred tank agitated by a six-blade, disk style turbine. The working fluid was air. Mean and fluctuating velocities were measured between the blades of the impeller with a probe mounted on the spinning impeller. Mean velocities, turbulent velocities, one-dimensional energy spectra, and Eulerian autocorrelation functions were measured in the impeller stream by using the shielded hot-wire anemometer of Gunkel et al. (1971) which permits the measurement of turbulence parameters in flows of very high turbulence intensity. Reliable impeller pumping capacities were obtained yielding Qrad/ND3 = 1.0 at the impeller periphery. An energy balance on a control volume containing the impeller and the impeller stream showed that the energy put into the tank via the impeller appeared as a net efflux of kinetic energy leaving the control volume. Therefore, most of the energy input to the tank is dissipated in the bulk of the tank.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 204-207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 939-949 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulence parameters were measured in the bulk of turbulent stirred tanks of 45.7 and 91.4 cm diameter with air as the working fluid. Three types of turbine impellers were studied ranging in diameter from 22.8 to 45.7 cm. The turbulence in the bulk of the tank was essentially homogeneous and isotropic. The normalized one-dimensional energy spectra and the Eulerian autocorrelation functions were approximately the same throughout the tank and for all tanks, impellers, and operating conditions. The space averaged turbulent velocities were correlated by using the turbulent energy equation. A transformation of the measured spectra from the frequency space to the wave number space was accomplished. Integration of the dissipation spectra in the wave number space confirmed that most of the energy input is dissipated in the bulk of the tank through the turbulent motion. The results were extended to low viscosity liquid systems and used to interpret the data on mass transfer from suspended particles.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 24 (1989), S. 875-884 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Under electron ionization (EI) conditions, porphyrins yield unusually high intensities of doubly charged molecular and fragment ions. These doubly charged ions offer unique opportunities for the structure elucidation of porphyrins by tandem mass spectrometry (MS/MS). First, they fragment to a greater extent than the corresponding singly charged ions under both EI/MS and EI/MS/MS conditions. Second, doubly and singly charged porphyrin ions often fragment via different pathways, and can therefore yield different structural information. This paper describes several ways in which analyses of doubly charged porphyrin ions with a triple quadrupole tandem mass spectrometer can be useful in structure elucidation of porphyrins. The effect of the metal atom on the fragmentation of metalloporphyrins in an EI source is demonstrated by correlating the extent of doubly charged fragment ion formation to a stability index. Doubly charged porphyrin ions are shown to yield predominantly doubly charged daughter ions upon collisionally activated dissociation (CAD), and are also shown to fragment to a greater extent than corresponding singly charged porphyrin ions. Advantages and disadvantages of doubly charged porphyrin ion MS/MS for structure elucidation are discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 20 (1991), S. 245-254 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A mathematical model has been developed for the quantitative x-ray fluorescence spectrometry of small spherical samples, e.g. targets containing diagnostic materials for inertial confinement fusion experiments. The model corrects for matrix effects in a multi-layer spherical geometry much as existing programs now do for thin films or bulk samples. Attenuation effects have been found to be greater in a shell geometry than in a comparable thin-film geometry because multiple passes through the shell are possible and because many paths in or out are nearly tangential to the shell. In both cases the path is longer and attenuation is greater. The model for primary fluorescence from uniform shells has also been extended to approximate the fluorescence from non-uniform shells. This allows one to predict how experimental results would vary with sample mounting if excess material were oriented toward or away from the x-ray beam or the detector or away from both. Finally, a simplified model for estimating the magnitude of secondary fluorescence effects is presented.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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