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  • Analytical Chemistry and Spectroscopy  (1)
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  • Analytical Chemistry and Spectroscopy  (1)
  • Chemistry  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 19 (1984), S. 153-159 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of 5,6,6a,7,12,12a-hexahydrobenzo[a]anthracene and 2-methoxy, 3-methoxy-, 4-methoxy and 1-methyl-4-methoxy derivatives are reported. Among the fragment ions observed under electron impact ionization, [C8H8]+· and [M—C8H8]+· can be generated by a retro-Diels-Alder process. Studies of metastable ion reactions show these ions to be formed by fragmentation directly from the molecular ion. The CA spectra of the [C8H8]+· ions from the subject compounds were compared with spectra from ions of the same composition from various sources. From these data, kinetic energy release measurements and stereochemical considerations, it is concluded that these ions are formed by a stepwise, rather than a concerted mechanism.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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