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  • Analytical Chemistry and Spectroscopy  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 11 (1978), S. 457-460 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study of several linear and branched alkanes indicates that the temperature dependence of 13C chemical shifts is a complex phenomenon in which several non-additive effects may be operative. The chemical shift temperature coefficients dδ/dT do, however, reveal some systematic trends which could be helpful in the assignments of 13C resonances. An empirical equation is proposed (akin to that of Grant and Paul for 13C chemical shifts) which accurately correlates all the data obtained near ambient temperatures.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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