ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The decomposing molecular cations derived from (substituted) 2-nitrothiobenzamides fragment by complex rearrangement reactions. When the alkyl substituents (R) attached to N are methyl, the major fragmentations are [M]+· → [M—SO]+· and [M—SO]+· → [(M—SO)+·-R·]+. This remains a basic pathway when R ≥ Et, but other rearrangements are also observed. For example, when R=Et, additional competitive processes are [M]+· → [M—HO·]+ and [M]+· → [M—C2H4O]+·.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210151209
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