ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
High-resolution Stokes and anti-Stokes Raman spectra of isotopically pure 127I79Br were recorded with excitation by argon ion laser radiation using CCD camera detection and a scanning multi-channel technique. The observed spectra show a complex rotational-vibrational structure, which can be explained in terms of Q branches, S band heads, unresolved O branches and corresponding hot band transitions. The spectral band shapes of the fundamental vibrational transitions and of several overtones were studied as a function of laser power and excitation wavelength. A symmetry principle between Stokes and anti-Stokes spectra is also demonstrated. In addition, hyperfine structure in the electronic Raman spectra of atomic 127I and 79Br was observed under high resolution.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250230608
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