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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 4 (1975), S. 581-590 
    ISSN: 1572-8927
    Keywords: Aqueous ; carbohydrates ; molar heat of fusion of water ; differential scanning calorimeter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The freezing of aqueous solutions of carbohydrates has been studied using differential scanning calorimetry. The reduction in the molar heat of fusion of water is attributed to the nonfreezing of a proportion of the water in the presence of the dissolved carbohydrate. The effects of concentration and molecular weight have been investigated.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 5 (1976), S. 799-806 
    ISSN: 1572-8927
    Keywords: Aqueous ; sodium carboxymethylcellulose ; differential scanning calorimeter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A differential scanning calorimeter has been used to study the nonfreezing of water in a series of solutions of sodium carboxymethylcellulose. In particular, the effects of molecular weight, degree of substitution, and particle size have been investigated. The results show that large amounts of water are associated with all the samples of sodium carboxymethylcellulose, suggesting a multilayer arrangement of water molecules about the solute. A change in degree of substitution has some effect on the hydration, but it appears less significant than a change in molecular weight.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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