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  • Aspergillus japonicus  (1)
  • Stannylene template  (1)
  • 1
    ISSN: 1432-072X
    Schlagwort(e): Aspergillus japonicus ; Lignin related aromatics ; Degradation of aromatic compounds ; Decarboxylation, oxidation, reduction, demethylation and hydroxylation of aromatics ; Aromatic ring cleavage
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract Aspergillus japonicus metabolizes a wide variety of aromatic compounds, some of them resulting from lignin degradation. The efficient conversion of such compounds is related to the efficiency shown by this fungus in degrading the aromatic portion of lignocarbohydrate complexes. The rate and extent of degradation of simpler aromatics is affected by cellobiose which enhances their degradation but there are examples in which it is inhibitory. The organism was capable of the following activities: Non-oxidative and oxidative decarboxylations, aromatic alcohol and aldehyde oxidation, aromatic acid reduction, side chain oxidation, demethylation of aromatic compounds, aromatic ring hydroxylation and aromatic ring cleavage. A scheme is shown for the biodegradative pathways of phenylpropanoids and derived compounds in A. japonicus. This versatile fungus seems to have more rapid rates and a wider spectrum of biodegradative activities than other fungi previously tested.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 1159-1167 
    ISSN: 0009-2940
    Schlagwort(e): Oligolactones, macrocyclic ; Macrocyclization ; Stannylene template ; Template synthesis ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Dibutylstannylene-mediated macrolactonization of methyl 4,6-O-benzylidene-&7alpha;-D-glucopyranoside (2) with glutaryl and phthaloyl dichloride yields the respective dilactones 6e and 6f and parallel tetralactones 5e and 5f as well as the antiparallel tetralactone 4e in the case of glutarylation. The reaction with malonyl dichloride yields a negligible amount of the parallel tetralactone 5d and that of fumaryl and isophthaloyl dichloride yields polyesters only, a byproduct in all these reactions. The mechanism of stannylene-medidted macrolactonization is discussed incorporating data pertaining to known hexa- and octalactone formation when succinyl dichloride is used. A correlation between stannylene dimer symmetry and tetralactone constitutional isomer selectivity is introduced.
    Zusätzliches Material: 4 Tab.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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