ISSN:
0009-2940
Schlagwort(e):
Phosphinediyl transfer reactions
;
Azaphosphaboriridines
;
Azadiphosphiridines
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Azaphosphaboriridines and Azadiphosphiridines by Phosphinediyl Transfer ReactionsThe azaphosphaboriridines (4a - d) are obtained by the reaction of the corresponding chloro(trimethyl-silyl)posphines RP(Cl)SiMe3 (1a - d) with the iminoborane 2. Equally, reaction of 1a - c with the iminophosphine 5 leads to the azadiphosphiridines (8a - c) via an imino-λ3,λ5-diphosphene intermediate tBuN=P(CEt3)=PCH-(SiMe3)2 (7a).
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19911240415
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