Bibliothek

X
feed icon rss

Ihre E-Mail wurde erfolgreich gesendet. Bitte prüfen Sie Ihren Maileingang.

Leider ist ein Fehler beim E-Mail-Versand aufgetreten. Bitte versuchen Sie es erneut.

Vorgang fortführen?

Exportieren
Filter
  • Artikel: DFG Deutsche Nationallizenzen  (5)
  • Biochemistry and Biotechnology  (3)
  • dilatometry  (2)
Datenquelle
  • Artikel: DFG Deutsche Nationallizenzen  (5)
Materialart
Erscheinungszeitraum
Schlagwörter
  • 1
    Digitale Medien
    Digitale Medien
    Reatarding effect of nitrogen ylide for the polymerization of N-vinyl pyrrolidone (1990)
    Springer
    Colloid & polymer science 268 (1990), S. 645-648 
    Details
    ISSN: 1435-1536
    Schlagwort(e): β-picolinium-p-chlorophenacylide ; α-α azobisisobutyronitrile ; N-vinyl pyrrolidone ; dilatometry ; retarder ; kinetics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract β-Picolinium-p-chlorophenacylide (β-PCFY) acts as a retarder for polymerization of N-vinyl pyrrolidone. The polymerization runs were carried out at 60°C using benzene as an inert solvent. The kinetic equation for the present system may be written asR p α[β-PCPY]−1.0 [AIBN]0.66[N-VP]1.0. The value of overall energy of activation for polymerization in presence and absence ofβ-PCPY was computed as 44.0 and 42.3 kJ mol−1, respectively. The inverse relationship ofR p and¯M v withβ-PCPY suggests thatβ-PCPY acts as a polymerization retarder. The retarding effect is also evidenced by higher initiator exponent value and higher value of energy of activation in presence of ylide. A mechanism is also proposed in which polymer propagating chain combines with one ylide component to give resonance stabilized radical.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF01410406
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 2
    Digitale Medien
    Digitale Medien
    Copolymerization of zinc acrylate with acrylonitrile initiated by As2S3-styrene complex (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 34 (1994), S. 105-109 
    Details
    ISSN: 0959-8103
    Schlagwort(e): Zinc acrylate ; acrylonitrile ; As2S3-styrene complex ; copolymerization ; dilatometry ; kinetics ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Radical copolymerization of zinc acrylate (ZnA2) with acrylonitrile (AN), initiated by As2S3-styrene complex(I), in dimethyl Sulphoxide (DMSO) at 90 ± 0.1°C for 1.0h under inert atmosphere, yields non-alternating copolymers. The kinetic expression is Rp ∝ [I]0.33 [ZnA2]0.25 [AN]0.44, i.e. the system follows non-ideal kinetics, which is due to primary radical termination as well as degradative chain transfer reactions. The values for activation energy (E) and k2p/kt are 128kJ mol-1 and 8.57 × 10-7 litre mol-1 s-1, respectively. Thermal stability, solubility in different solvents, and IR and NMR spectra have been evaluated.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pi.1994.210340114
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 3
    Digitale Medien
    Digitale Medien
    Measurement and regulation of the culture reduction state in Clostridium acetobutylicum (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 38 (1991), S. 181-190 
    Details
    ISSN: 0006-3592
    Schlagwort(e): solventogenic metabolism ; NADH content ; NADH fluorescence ; continuous fermentation ; butanol biosynthesis ; Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: With a constant glucose feed concentration, the change in the continuous culture dillution rate resulted in an altered fermentation profile and the cellular NADH content. The cultures growing at high dillution rates demonstrated an oxidative metabolism low NADH and butanol concentrations. The low specific NADH flourescence (F/X) at high butanol production rates suggested that a rapid regeneration of NADH to NAD is essential for a high solventogenic culture activity. The culture florescence and butanol concentration remained constant in the solventogenic dilution rate range of D = 0.05-0.2 h-1 with an inverse relationship between the specific flourescence (F/X) and the specific butanol production rate, qB. Flourometric NADH observations were confirmed by enzymatic NADH determination. The stiochiometric “Fermentation Equation” was used to check the experimental data consistency and to investigate the role of the available biosynthetic and reduction energy on the culture metabolic activities under different growth conditions. The butanol concentration in the broth was stabilized in a fed-batch process when the culture NADH fluorescence was being controlled through the addition of fresh medium.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/bit.260380210
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 4
    Digitale Medien
    Digitale Medien
    NADH fluorscence in a carbon-limited fermentation (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 38 (1991), S. 191-195 
    Details
    ISSN: 0006-3592
    Schlagwort(e): continuous flow acetone-butanol fermentations ; reduction energy ; solvent production activity ; inlet sugar concentrations ; Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The continuous flow acetone-butanol fermentation conducted at lowered inlet feed sugar concentrations and at a constant dilution rate D =0.075 h-1 demonstrated a significant decreases in the availability of the cell population “reduction energy” (F/X), resulting in an exclusive accumulation of intermediate acids under those conditions. The cultures resumed its solvent production activity when the inlet sugar concentration in the feed stream was increased from 20 to 40 g/L at the same low growth/dilution rates. A linear correlation between the culture reduction content (F/X) and the specific butanol rate (qB) was observed under the present conditions, indicating the necessity of the NADH availability for the increased solvent production.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/bit.260380211
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
    Volltext
  • 5
    Digitale Medien
    Digitale Medien
    Representation of culture transition states in A. suboxydans (1998)
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 73 (1998), S. 23-30 
    Details
    ISSN: 0268-2575
    Schlagwort(e): vitamin C ; structured mathematical model ; continuous culture kinetics ; sorbose ; sorbitol ; Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The kinetics of the biotransformation of D-sorbitol to L-sorbose by Acetobacter suboxydans (NRRL B-72) features both substrate and product inhibition. Model-based reactor operating strategies can eliminate the inhibitions and improve the yield and productivity of the fermentation. Unstructured models are usually unable to acknowledge complex intracellular physiological changes and therefore their application to dynamic growth conditions is limited. By considering RNA as a bottleneck growth limiting compound a structured mathematical model was developed to describe the transient growth of Acetobacter suboxydans. The model parameters were determined by a non-linear regression technique which minimized the deviation between the model prediction and the experimental (extracellular and intracellular) continuous culture data. The model was used to simulate the transient culture behaviour during the step-down in the dilution rates (from 0·1 h-1 to 0·05 h-1) in the continuous culture experiments. The experimental results and the model simulation results showed reasonable agreement. © 1998 Society of Chemical Industry
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
    Artikel (Nationallizenzen)
Schließen ⊗
Diese Webseite nutzt Cookies und das Analyse-Tool Matomo. Weitere Informationen finden Sie hier...