ISSN:
0268-2575
Keywords:
lanthanides
;
organophosphorus
;
extraction
;
kinetts
;
inhibition
;
EDTA
;
Chemistry
;
Biochemistry and Biotechnology
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The kinetic behavior of lanthanide extraction from HAc-NaAc-EDTA media with three acidic phosphorus extractants(HL), bis(2-ethylhexyl)phosphoric acid (HDEHP), 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH(EHP)) and bis(2,2,4-trimethylpentyl)phosphinic acid (H(DTMPP)) in n-octane solution is reported. The observed rate constants, ko for the metals (M) lanthanum, neodymium, gadolinium, holmium and lutetium with these three extractants were determined under vigorous mixing. The rate equation for extraction was determined to be: \documentclass{article}\pagestyle{empty}\begin{document}$ \begin{array}{*{20}c} {- {\rm d}[{\rm M}]/{\rm d}t = k'_{\rm o} \left[{\rm M} \right]\left[{{\rm HL}} \right]_{\rm o}^{\rm 0} \left[{{\rm H}^ +} \right]^0 \left[{{\rm EDTA}} \right]^{-1}} \\ {= k'_{\rm o} \left[{\rm M} \right]\left[{{\rm EDTA}} \right]^{- 1}} \\ \end{array} $\end{document} A mechanism has been proposed for the extraction reaction under the experimental conditions. For a given metal the rate constant as a function of ligand followed the order HDEHP 〉 HEH(EHP) 〉 H(DTMPP), the decrease from HDEHP to H(DTMPP) being less than an order of magnitude. It was also found that the rate constants for these metals and yttrium bear an inverse relationship to the stability constants of their complexes with EDTA.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
Permalink
