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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 6 (1996), S. 406-408 
    ISSN: 1057-9257
    Schlagwort(e): conjugated polymers ; electroluminescence ; light emitting diodes ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Elektrotechnik, Elektronik, Nachrichtentechnik , Physik
    Notizen: Regioregular poly(4,4′-didecyl-2,2′-bithiophene) with exclusively head-to-head and tail-to-tail couplings between adjacent alkylated thiophene rings was studied as a potential material for the active layer in light-emitting diodes (LEDs). Readily visible green light was derived from a single layer LED structure. The electroluminescence (EL) spectrum peaks at 2.2 eV. Excitation of photoluminescence (PL) resulted in green light with the spectrum peaked at 2.3 eV. Additionally to the electroluminescence and photoluminescence measurements, the absorption spectrum is reported. Determination of the optical energy gap gave Eg equal to 2.9 eV. The same experiments performed for another regioregular polyalkylthiophene system (with only head-to-tail couplings) showed extremely poor EL and PL intensity, below the sensitivity of our spectrometer. The difference in yield of photo- and electroluminescence is likely interpreted in terms of trapping of excitons in conjugated blocks separated by head-to-head dyads, where they decay. Non-planarity of the polymer backbone also influences the relative positions of singlet and triplet states.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    The @Anatomical Record 242 (1995), S. 411-416 
    ISSN: 0003-276X
    Schlagwort(e): Blood vessles ; Nasal mucosa ; Human fetus ; Corrosion casting ; Life and Medical Sciences ; Cell & Developmental Biology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin
    Notizen: Background: The vasculature of the nasal mucosa in the human fetus so far has not been investigated morphologically by modern techniques.Methods: Nasal blood vessels were studies in 18-21-week-old human fetuses by corrosion casting and scanning electron microscopy.Results: The general vascular architecture was similar to that described for adult humans, with (1) a dense network of subepithelial capillaries, (2) a mucosal layer of larger vessles, predominantly veins, and (3) large arteries located near the perichondrium. Specific vessel types characteristic of the nasal mucosa and important for its functions in adults, such as cavernous veins or cushion veins, were, however, absent in the fetuses, although probable precursor forms of cushion veins could be observed. The arteriovenous anastomoses had the form of short bridges, and no tortuous or glomerular anastomoses present in the mature nasal mucosa were found.Conclusions: The underdevelopment of some vascular areas is postulated to reflect the functional immaturily of the respiratory system in the fetus. © 1995 Wiley-Liss, Inc.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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