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  • 2,3-μ-Hydro-1,2,3-azoniadiborata-l-cyclopropenes  (1)
  • Borylene complexes  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Protolysis of Tri-tert-butylazadiboriridine: Formation of a B-H-B Bridge in Unusual Coordination (1995)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 128 (1995), S. 99-103 
    Details
    ISSN: 0009-2940
    Keywords: Tri-tert-butylazadiboriridine ; (Hydroboryl)(methoxyboryl)amine ; 2,3-μ-Hydro-1,2,3-azoniadiborata-l-cyclopropenes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The B—B bond of tri-tert-butylazadiboriridine [—NR—BR—BR—] (R = tBu; 1) is oxidized by MeOH to give the (hydroboryl)(methoxyboryl)amine H—BR=NR-BR(OMe) (2a). μ-2,3-Hydroazoniadiborata-1-cyclopropenes [=NR—BR(X)—μH—BR=] (3a, 3c-e) are formed by the action of the acids HX upon 1. A similar hydrogen bridge as in 3a-e is formed during the hydroboration of 1 by catecholborane, yielding 3f. A B atom is identified in the products 3a-f to be planarly coordinated by four atoms, two of which are forming a BHB three-center bond with that B atom. This is a novel bonding situation in boron chemistry. The structures of the products are deduced from 1H-, 11B-, and 13C-NMR spectra and are confirmed by X-ray structural analyses of 2a, 3a, and 3c.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19951280203
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  • 2
    Electronic Resource
    Electronic Resource
    New Borylene Complexes of the Type [μ-BX{.5-C5H4Me)MN(CO)2}2]: Substitution Reactions at the Metal-Coordinated Borylene Moiety (1997)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1295-1298 
    Details
    ISSN: 0009-2940
    Keywords: Boron ; Manganese ; Borylene complexes ; Reactions at metal-coordinated boron ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction of the air- and water-stable borylene complex [μ-BNMe2{.5-C5H4Me)Mn(CO)2}2] (1a) with a solution of Hcl in Et2O affords the correspondin chloroborylene complex [μ-Chloroborylenebis{dicarbonyl(.5-methylcyclopentadienyl)manganese}(Mn-Mn)] (2). This compound easily undergoes further substitution reactions with protic reagents such as primary amines, alcohols and water at the metal coordinated borylene moiety with elimination of HCl, giving new products of the type [μ-BX{.4-C5H4ME)Mn(CO)2}2] (3a, ab: X=NHtBu, NHPh; 4a, b: × = OMe, OEt; 5: X= Oh}. All borylene complexes were isolated as crystalline solids in good yield and characterized by multinuclear NMR methods and IR spectroscopy in solution. In addition, the structure of 4b in the crystalline state was determined by a single-crystal X-ray study.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19971300918
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    Paper (German National Licenses)
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