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Carbon Dioxide as an Alternative C1 Synthetic Unit: Activation by Transition-Metal Complexes (1988)

Behr, Arno

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 27 (1988), S. 661-678

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Details

ISSN: 0570-0833

Schlagwort(e): Carbon dioxide ; C1 synthetic unit ; Transition metals ; C-C coupling ; Homogeneous catalysis ; Catalysis ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The carbon dioxide molecule has been of limited importance as a synthetic unit in organic chemistry. When it is coordinated to transition metals, however, completely new possibilities arise; CO2 can bond to metal complexes in a variety of ways and can enter into insertion and coupling reactions, or become catalytically attached to other substrates. The formation of C—C bonds between carbon dioxide and unsaturated hydrocarbons under conditions of homogeneous catalysis makes available new synthetic routes to industrially interesting organic compounds.

Zusätzliches Material: 11 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/anie.198806611

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